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Synthesis, characterization and performance of Cd1-xInxTe compound for solar cell applications

Identifieur interne : 000395 ( Main/Repository ); précédent : 000394; suivant : 000396

Synthesis, characterization and performance of Cd1-xInxTe compound for solar cell applications

Auteurs : RBID : Pascal:13-0194031

Descripteurs français

English descriptors

Abstract

Cd1-xInxTe (x = 0.0, 0.2, 0.4, 0.6, 0.8 and 1.0) samples have been synthesized chemically using wet chemical method from precursor compounds, CdS04, InCl3, and TeCl4. The hydroxide form of the solution mixture was obtained by using ammonia solution and the pH of the mixture was adjusted to 9. A suitable amount of NaBH4 solution was added to reduce the hydroxide phase to the metalloid alloy. The crystal structure has been studied using powder X-ray diffraction (XRD) and scanning electron microscopy (SEM) measurements. The 300 °C annealed samples revealed a cubic crystal structure. The morphology of the prepared samples is very fine and the average diameter is between 1 and 2.5 μm. The optical properties were determined using UV-vis-NIR spectrophotometer and band gap energy of 1.37 eV for Cd0.6In0.4Te was obtained. The best photovoltaic conversion efficiency of 1.89% was obtained for the Cd0.6In0.4Te sample with a short circuit current density (Jsc) of 15.3 mA cm-2, an open circuit voltage (Voc) of 0.668 V, and a filling factor (FF) of 69.31%.

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Pascal:13-0194031

Le document en format XML

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<title xml:lang="en" level="a">Synthesis, characterization and performance of Cd
<sub>1-x</sub>
In
<sub>x</sub>
Te compound for solar cell applications</title>
<author>
<name sortKey="Shenouda, Atef Y" uniqKey="Shenouda A">Atef Y. Shenouda</name>
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<s1>Central Metallurgical R&D Institute (CMRDI), Tebbin, P.O. Box 87 Helwan</s1>
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<country>Égypte</country>
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<author>
<name sortKey="Rashad, Mohamed M" uniqKey="Rashad M">Mohamed M. Rashad</name>
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<s1>Central Metallurgical R&D Institute (CMRDI), Tebbin, P.O. Box 87 Helwan</s1>
<s2>Cairo 11412</s2>
<s3>EGY</s3>
<sZ>1 aut.</sZ>
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<country>Égypte</country>
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<author>
<name sortKey="Chow, Lee" uniqKey="Chow L">Lee Chow</name>
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<s1>Department of Physics, University of Central Florida</s1>
<s2>Orlando, FL 32816</s2>
<s3>USA</s3>
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<country>États-Unis</country>
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<idno type="ISSN">0925-8388</idno>
<title level="j" type="abbreviated">J. alloys compd.</title>
<title level="j" type="main">Journal of alloys and compounds</title>
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<term>Ammonia</term>
<term>Annealing</term>
<term>Band structure</term>
<term>Cadmium tellurides</term>
<term>Chemical method</term>
<term>Crystal growth from solutions</term>
<term>Crystalline structure</term>
<term>Cubic crystals</term>
<term>Cubic lattices</term>
<term>Electronic properties</term>
<term>Energy gap</term>
<term>Fill factor</term>
<term>Hydroxides</term>
<term>Indium</term>
<term>Indium chloride</term>
<term>Infrared spectrum</term>
<term>Microstructure</term>
<term>Morphology</term>
<term>Near infrared spectrum</term>
<term>Optical properties</term>
<term>Photovoltaic conversion</term>
<term>Precursor</term>
<term>Scanning electron microscopy</term>
<term>Short circuit currents</term>
<term>Solar cell</term>
<term>Ultraviolet radiation</term>
<term>Volatile organic compound</term>
<term>Wet process</term>
<term>X ray diffraction</term>
<term>pH</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Cellule solaire</term>
<term>Procédé voie humide</term>
<term>Méthode chimique</term>
<term>Précurseur</term>
<term>Chlorure d'indium</term>
<term>Hydroxyde</term>
<term>Croissance cristalline en solution</term>
<term>Ammoniac</term>
<term>pH</term>
<term>Structure cristalline</term>
<term>Diffraction RX</term>
<term>Microscopie électronique balayage</term>
<term>Recuit</term>
<term>Cristal cubique</term>
<term>Réseau cubique</term>
<term>Composé organique volatil</term>
<term>Microstructure</term>
<term>Morphologie</term>
<term>Propriété optique</term>
<term>Rayonnement UV</term>
<term>Spectre IR proche</term>
<term>Spectre IR</term>
<term>Bande interdite</term>
<term>Propriété électronique</term>
<term>Structure bande</term>
<term>Conversion photovoltaïque</term>
<term>Courant court circuit</term>
<term>Facteur remplissage</term>
<term>Tellurure de cadmium</term>
<term>Indium</term>
<term>InCl3</term>
<term>NaBH4</term>
<term>8460J</term>
<term>8110D</term>
<term>6166</term>
<term>7820</term>
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<div type="abstract" xml:lang="en">Cd
<sub>1-x</sub>
In
<sub>x</sub>
Te (x = 0.0, 0.2, 0.4, 0.6, 0.8 and 1.0) samples have been synthesized chemically using wet chemical method from precursor compounds, CdS0
<sub>4</sub>
, InCl
<sub>3</sub>
, and TeCl
<sub>4</sub>
. The hydroxide form of the solution mixture was obtained by using ammonia solution and the pH of the mixture was adjusted to 9. A suitable amount of NaBH
<sub>4</sub>
solution was added to reduce the hydroxide phase to the metalloid alloy. The crystal structure has been studied using powder X-ray diffraction (XRD) and scanning electron microscopy (SEM) measurements. The 300 °C annealed samples revealed a cubic crystal structure. The morphology of the prepared samples is very fine and the average diameter is between 1 and 2.5 μm. The optical properties were determined using UV-vis-NIR spectrophotometer and band gap energy of 1.37 eV for Cd
<sub>0.6</sub>
In
<sub>0.4</sub>
Te was obtained. The best photovoltaic conversion efficiency of 1.89% was obtained for the Cd
<sub>0.6</sub>
In
<sub>0.4</sub>
Te sample with a short circuit current density (J
<sub>sc</sub>
) of 15.3 mA cm
<sup>-2</sup>
, an open circuit voltage (V
<sub>oc</sub>
) of 0.668 V, and a filling factor (FF) of 69.31%.</div>
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In
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<s1>RASHAD (Mohamed M.)</s1>
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<s2>Cairo 11412</s2>
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<s0>Cd
<sub>1-x</sub>
In
<sub>x</sub>
Te (x = 0.0, 0.2, 0.4, 0.6, 0.8 and 1.0) samples have been synthesized chemically using wet chemical method from precursor compounds, CdS0
<sub>4</sub>
, InCl
<sub>3</sub>
, and TeCl
<sub>4</sub>
. The hydroxide form of the solution mixture was obtained by using ammonia solution and the pH of the mixture was adjusted to 9. A suitable amount of NaBH
<sub>4</sub>
solution was added to reduce the hydroxide phase to the metalloid alloy. The crystal structure has been studied using powder X-ray diffraction (XRD) and scanning electron microscopy (SEM) measurements. The 300 °C annealed samples revealed a cubic crystal structure. The morphology of the prepared samples is very fine and the average diameter is between 1 and 2.5 μm. The optical properties were determined using UV-vis-NIR spectrophotometer and band gap energy of 1.37 eV for Cd
<sub>0.6</sub>
In
<sub>0.4</sub>
Te was obtained. The best photovoltaic conversion efficiency of 1.89% was obtained for the Cd
<sub>0.6</sub>
In
<sub>0.4</sub>
Te sample with a short circuit current density (J
<sub>sc</sub>
) of 15.3 mA cm
<sup>-2</sup>
, an open circuit voltage (V
<sub>oc</sub>
) of 0.668 V, and a filling factor (FF) of 69.31%.</s0>
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<fC02 i1="03" i2="3">
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<s0>001B80A40E</s0>
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<fC02 i1="05" i2="X">
<s0>230</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE">
<s0>Cellule solaire</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG">
<s0>Solar cell</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA">
<s0>Célula solar</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE">
<s0>Procédé voie humide</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG">
<s0>Wet process</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA">
<s0>Procedimiento vía húmeda</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE">
<s0>Méthode chimique</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG">
<s0>Chemical method</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA">
<s0>Método químico</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE">
<s0>Précurseur</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG">
<s0>Precursor</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA">
<s0>Precursor</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE">
<s0>Chlorure d'indium</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG">
<s0>Indium chloride</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA">
<s0>Indio cloruro</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE">
<s0>Hydroxyde</s0>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG">
<s0>Hydroxides</s0>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA">
<s0>Hidróxido</s0>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE">
<s0>Croissance cristalline en solution</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG">
<s0>Crystal growth from solutions</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE">
<s0>Ammoniac</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG">
<s0>Ammonia</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Amoníaco</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>pH</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG">
<s0>pH</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA">
<s0>pH</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE">
<s0>Structure cristalline</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG">
<s0>Crystalline structure</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Estructura cristalina</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE">
<s0>Diffraction RX</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG">
<s0>X ray diffraction</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA">
<s0>Difracción RX</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Microscopie électronique balayage</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>Scanning electron microscopy</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Microscopía electrónica barrido</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE">
<s0>Recuit</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG">
<s0>Annealing</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA">
<s0>Recocido</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE">
<s0>Cristal cubique</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG">
<s0>Cubic crystals</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA">
<s0>Cristal cúbico</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE">
<s0>Réseau cubique</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG">
<s0>Cubic lattices</s0>
<s5>15</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE">
<s0>Composé organique volatil</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG">
<s0>Volatile organic compound</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA">
<s0>Compuesto orgánico volátil</s0>
<s5>16</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE">
<s0>Microstructure</s0>
<s5>29</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG">
<s0>Microstructure</s0>
<s5>29</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA">
<s0>Microestructura</s0>
<s5>29</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE">
<s0>Morphologie</s0>
<s5>30</s5>
</fC03>
<fC03 i1="18" i2="X" l="ENG">
<s0>Morphology</s0>
<s5>30</s5>
</fC03>
<fC03 i1="18" i2="X" l="SPA">
<s0>Morfología</s0>
<s5>30</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE">
<s0>Propriété optique</s0>
<s5>31</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG">
<s0>Optical properties</s0>
<s5>31</s5>
</fC03>
<fC03 i1="19" i2="X" l="SPA">
<s0>Propiedad óptica</s0>
<s5>31</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE">
<s0>Rayonnement UV</s0>
<s5>32</s5>
</fC03>
<fC03 i1="20" i2="X" l="ENG">
<s0>Ultraviolet radiation</s0>
<s5>32</s5>
</fC03>
<fC03 i1="20" i2="X" l="SPA">
<s0>Radiación ultravioleta</s0>
<s5>32</s5>
</fC03>
<fC03 i1="21" i2="X" l="FRE">
<s0>Spectre IR proche</s0>
<s5>33</s5>
</fC03>
<fC03 i1="21" i2="X" l="ENG">
<s0>Near infrared spectrum</s0>
<s5>33</s5>
</fC03>
<fC03 i1="21" i2="X" l="SPA">
<s0>Espectro IR próximo</s0>
<s5>33</s5>
</fC03>
<fC03 i1="22" i2="X" l="FRE">
<s0>Spectre IR</s0>
<s5>34</s5>
</fC03>
<fC03 i1="22" i2="X" l="ENG">
<s0>Infrared spectrum</s0>
<s5>34</s5>
</fC03>
<fC03 i1="22" i2="X" l="SPA">
<s0>Espectro IR</s0>
<s5>34</s5>
</fC03>
<fC03 i1="23" i2="X" l="FRE">
<s0>Bande interdite</s0>
<s5>35</s5>
</fC03>
<fC03 i1="23" i2="X" l="ENG">
<s0>Energy gap</s0>
<s5>35</s5>
</fC03>
<fC03 i1="23" i2="X" l="SPA">
<s0>Banda prohibida</s0>
<s5>35</s5>
</fC03>
<fC03 i1="24" i2="X" l="FRE">
<s0>Propriété électronique</s0>
<s5>36</s5>
</fC03>
<fC03 i1="24" i2="X" l="ENG">
<s0>Electronic properties</s0>
<s5>36</s5>
</fC03>
<fC03 i1="24" i2="X" l="SPA">
<s0>Propiedad electrónica</s0>
<s5>36</s5>
</fC03>
<fC03 i1="25" i2="X" l="FRE">
<s0>Structure bande</s0>
<s5>37</s5>
</fC03>
<fC03 i1="25" i2="X" l="ENG">
<s0>Band structure</s0>
<s5>37</s5>
</fC03>
<fC03 i1="25" i2="X" l="SPA">
<s0>Estructura banda</s0>
<s5>37</s5>
</fC03>
<fC03 i1="26" i2="X" l="FRE">
<s0>Conversion photovoltaïque</s0>
<s5>38</s5>
</fC03>
<fC03 i1="26" i2="X" l="ENG">
<s0>Photovoltaic conversion</s0>
<s5>38</s5>
</fC03>
<fC03 i1="26" i2="X" l="SPA">
<s0>Conversión fotovoltaica</s0>
<s5>38</s5>
</fC03>
<fC03 i1="27" i2="3" l="FRE">
<s0>Courant court circuit</s0>
<s5>39</s5>
</fC03>
<fC03 i1="27" i2="3" l="ENG">
<s0>Short circuit currents</s0>
<s5>39</s5>
</fC03>
<fC03 i1="28" i2="3" l="FRE">
<s0>Facteur remplissage</s0>
<s5>40</s5>
</fC03>
<fC03 i1="28" i2="3" l="ENG">
<s0>Fill factor</s0>
<s5>40</s5>
</fC03>
<fC03 i1="29" i2="3" l="FRE">
<s0>Tellurure de cadmium</s0>
<s2>NK</s2>
<s5>41</s5>
</fC03>
<fC03 i1="29" i2="3" l="ENG">
<s0>Cadmium tellurides</s0>
<s2>NK</s2>
<s5>41</s5>
</fC03>
<fC03 i1="30" i2="X" l="FRE">
<s0>Indium</s0>
<s2>NC</s2>
<s5>42</s5>
</fC03>
<fC03 i1="30" i2="X" l="ENG">
<s0>Indium</s0>
<s2>NC</s2>
<s5>42</s5>
</fC03>
<fC03 i1="30" i2="X" l="SPA">
<s0>Indio</s0>
<s2>NC</s2>
<s5>42</s5>
</fC03>
<fC03 i1="31" i2="X" l="FRE">
<s0>InCl3</s0>
<s4>INC</s4>
<s5>46</s5>
</fC03>
<fC03 i1="32" i2="X" l="FRE">
<s0>NaBH4</s0>
<s4>INC</s4>
<s5>47</s5>
</fC03>
<fC03 i1="33" i2="X" l="FRE">
<s0>8460J</s0>
<s4>INC</s4>
<s5>71</s5>
</fC03>
<fC03 i1="34" i2="X" l="FRE">
<s0>8110D</s0>
<s4>INC</s4>
<s5>72</s5>
</fC03>
<fC03 i1="35" i2="X" l="FRE">
<s0>6166</s0>
<s4>INC</s4>
<s5>73</s5>
</fC03>
<fC03 i1="36" i2="X" l="FRE">
<s0>7820</s0>
<s4>INC</s4>
<s5>74</s5>
</fC03>
<fN21>
<s1>175</s1>
</fN21>
<fN44 i1="01">
<s1>OTO</s1>
</fN44>
<fN82>
<s1>OTO</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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